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My mom has very round breasts too actually. They're actually a similar shape to Kim's but Kim's are perkier as she's younger. I've always thought her boobs looked too small to be a C (that was before I knew about difference in band sizes) but you have a good point. I think Katy Perry has claimed both a 32DD and a 32D so she might be in between the two. Also keep in mind Katy has a very small frame so they look bigger in comparison to her body. My friend met Katy and she said she was shocked at how tiny Katy was frame wise. Either way, Kelly Brook is a 32E and there is now way my mother is bigger than her. My mom has a similar shape to Kelly as well, maybe even rounder. http://www.fotolive.org/r_celebrity_photos_40_kelly_brook_photos_216_kelly_brook_photos_1183.html

Also, since you're good at judging sizes could you tell me how big you think Bar Refaeli is? This is my dream size. I probably won't get close seeing as I'm a 34AAA to begin with but yeah it doesn't hurt to dream. I would guess Bar to be a small 34D.
http://omgoddesses.soup.io/post/97662033/Bar-Refaeli-Bikini-Candids-in-Mexico